Novel catalytic asymmetric sulfoxidation in water using the hypervalent iodine reagent iodoxybenzene.

نویسندگان

  • H Tohma
  • S Takizawa
  • H Morioka
  • T Maegawa
  • Y Kita
چکیده

A new catalytic asymmetric oxidation of sulfides to sulfoxides in water using the hypervalent iodine(V) reagent iodoxybenzene (PhIO2) has been developed. This methodology is distinctly different from the previously reported use of cyclodextrins or biological catalysts and provides a new route to asymmetric sulfoxidation in water.

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عنوان ژورنال:
  • Chemical & pharmaceutical bulletin

دوره 48 3  شماره 

صفحات  -

تاریخ انتشار 2000